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LABORATORIUM OPERASI TEKNIK KIMIA

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REVISI PEMBAHASAN

Pengaruh Waktu Reaksi Terhadap Densitas

Pengaruh Waktu Reaksi Terhadap Viskositas

Berdasarkan jurnal berjudul “Pengaruh Rasio Reaktan dan Jumlah Katalis Terhadap Konversi Minyak Jagung Menjadi Metil Ester” dijelaskan bahwa penggunaan katalis untuk mempercepat laju reaksi harus mempunyai perbandingan yang sesuai dengan bilangan tersebut. dari reaktan yang digunakan. Apabila perbandingan yang digunakan antara reaktan dan katalis tidak tepat maka akan mempengaruhi hasil konversi pada saat reaksi berlangsung. Oleh karena itu, untuk mendapatkan hasil konversi terbaik dalam proses reaksi, reaktan dan katalis yang digunakan harus memiliki perbandingan yang sesuai.

Berdasarkan jurnal yang berjudul “Pengaruh Waktu Pencampuran Pada Proses Pencampuran Asam Poli Laktat dengan Polyethylene Glycol-400 Terhadap Viskositas dan Densitas Bioplastik” dijelaskan bahwa pada suatu reaksi yang dilakukan dengan pencampuran yang konstan dari awal sampai akhir, maka semakin lama waktu yang dibutuhkan. waktu reaksi, semakin banyak produk yang terbentuk. Jadi, jika waktu reaksi semakin lama, maka resin urea formaldehida yang terbentuk akan semakin banyak. Berdasarkan Gambar 4.2 grafik analisis viskositas dapat disimpulkan bahwa variasi massa katalis yang terbaik adalah variasi massa katalis sebesar 2% dari total massa reaktan.

Hal ini disebabkan perubahan massa katalis 1% dan massa katalis 3% tidak mempunyai perbandingan yang sesuai dengan massa total reaktan sehingga mempengaruhi konversi pada saat reaksi.

Penentuan Orde Reaksi

Hal ini menunjukkan bahwa reaksi yang berlangsung merupakan reaksi yang lajunya dipengaruhi oleh konsentrasi dua reaktan yang berbeda dan dipangkatkan satu.

Gambar 4.2.3 Orde reaksi dari variasi katalis 1%
Gambar 4.2.3 Orde reaksi dari variasi katalis 1%

Identification of the substance/mixture and of the company/undertaking

  • Product identifier
  • Relevant identified uses of the substance or mixture and uses advised against
  • Emergency telephone number

Hazards identification

  • Classification of the substance or mixture GHS-US classification
  • Label elements GHS-US labelling
  • Unknown acute toxicity (GHS-US) No data available

P264 - Wash exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothes must not be allowed out of the workplace. P273 - Avoid release to the environment. P308+P313 - IF exposed or concerned: Get medical advice/attention P310 - Immediately call a POISON CENTER or doctor/physician P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P363 - Wash contaminated clothing before reuse.

Composition/information on ingredients

  • Substance

First aid measures

  • Description of first aid measures
  • Most important symptoms and effects, both acute and delayed
  • Indication of any immediate medical attention and special treatment needed Obtain medical assistance

P304+P340 - IF INHALED: move casualty to fresh air and make sure to rest in a position that facilitates breathing.

Firefighting measures

  • Extinguishing media
  • Special hazards arising from the substance or mixture
  • Advice for firefighters

Accidental release measures

  • For emergency responders
  • Environmental precautions
  • Methods and material for containment and cleaning up
  • Reference to other sections No additional information available

Methods for cleaning up : Absorb liquid spill in absorbent material eg: dry sand/earth/vermiculite.

Handling and storage

  • Precautions for safe handling
  • Conditions for safe storage, including any incompatibilities
  • Specific end use(s) No additional information available

Exposure controls/personal protection

  • Control parameters Formaldehyde, 37% w/w (50-00-0)
  • Exposure controls

Physical and chemical properties

  • Information on basic physical and chemical properties
  • Other information

Stability and reactivity

  • Reactivity
  • Chemical stability No data available
  • Possibility of hazardous reactions None
  • Conditions to avoid
  • Incompatible materials

Toxicological information

  • Information on toxicological effects

Ecological information

  • Toxicity
  • Bioaccumulative potential Formaldehyde, 37% w/w (50-00-0)
  • Mobility in soil Formaldehyde, 37% w/w (50-00-0)
  • Other adverse effects No additional information available

Disposal considerations

  • Waste treatment methods

Transport information

If the material has a flash point of less than 38 C (100 F), the bulk packaging requirements of 173.242 of this subchapter apply. TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling a (tr - tf)) Where: tr is the maximum average mass temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. DOT vessel storage: A - The material can be stored "on deck" or "below deck" on a cargo ship and on a passenger vessel.

Regulatory information

  • US Federal regulations Formaldehyde, 37% w/w (50-00-0)
  • US State regulations Formaldehyde, 37% w/w(50-00-0)

Class D, Division 2, Subdivision A - Highly toxic material causing other toxic effects. Class D, Division 2, Subdivision B - Toxic material causing other toxic effects. Class E - Corrosive material. Class D, Division 2, Subdivision A - Highly toxic material causing other toxic effects. Class D, Division 2, Subdivision B - Toxic material causing other toxic effects. Water. Listed on IARC (International Agency for Research on Cancer). Listed as a carcinogen on NTP (National Toxicology Program). Listed on the Canadian Ingredient Disclosure List.

Other information

The information in this safety data sheet is from available published sources and is believed to be accurate. No warranty, express or implied, is given and LabChem Inc assumes no liability arising from the use of this safety data sheet.

Sodium Carbonate, 1.0M (2.0N)

  • Identification 1.1. Identification
    • Recommended use and restrictions on use
  • Hazard(s) identification 2.1. Classification of the substance or mixture
    • GHS Label elements, including precautionary statements GHS-US labeling
    • Other hazards which do not result in classification Other hazards not contributing to the
    • Unknown acute toxicity (GHS US) Not applicable
    • Mixtures
    • Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact : Causes skin irritation
    • Immediate medical attention and special treatment, if necessary No additional information available
  • Fire-fighting measures
    • Suitable (and unsuitable) extinguishing media
    • Specific hazards arising from the chemical No additional information available
    • Special protective equipment and precautions for fire-fighters
    • Environmental precautions
    • Reference to other sections
  • Handling and storage 7.1. Precautions for safe handling
    • Appropriate engineering controls
    • Individual protection measures/Personal protective equipment Personal protective equipment
  • Physical and chemical properties 9.1. Information on basic physical and chemical properties
    • Other information No additional information available
  • Stability and reactivity 10.1. Reactivity
    • Possibility of hazardous reactions Reacts violently with acids
    • Conditions to avoid
    • Incompatible materials Strong oxidizers. Strong acids
  • Toxicological information 11.1. Information on toxicological effects
  • Ecological information 12.1. Toxicity
    • Persistence and degradability Sodium Carbonate, 1.0M (2.0N)
    • Bioaccumulative potential Sodium Carbonate, 1.0M (2.0N)
    • Mobility in soil No additional information available
  • Disposal considerations 13.1. Disposal methods
  • Transport information Department of Transportation (DOT)
  • Regulatory information 15.1. US Federal regulations
    • International regulations CANADA

Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact : Causes skin irritation. Immediate medical attention and special treatment, if necessary No additional information available No additional information available. NFPA Fire Hazard: 0 - Materials that will not burn under typical hazardous conditions, including intrinsically noncombustible materials such as concrete, stone, and sand.

Health : 1 Slight hazard - Irritation or minor reversible damage possible. Flammability : 0 Minimal hazard - Materials that do not burn. Physical: 0 Minimal Hazard - Materials that are normally stable even under fire conditions and will NOT react with water, polymerize, decompose, condense or self-react.

Material Safety Data Sheet

Urea MSDS

Chemical Product and Company Identification

RTECS: YR6250000

Contact Information

Sciencelab.com, Inc

CHEMTREC (24HR Emergency Telephone), call

Composition and Information on Ingredients

Composition

Hazards Identification

Potential Chronic Health Effects

First Aid Measures

Eye Contact

Skin Contact

Serious Skin Contact

Inhalation

Ingestion

Fire and Explosion Data

Explosion Hazards in Presence of Various Substances

Fire Fighting Media and Instructions

Accidental Release Measures

Small Spill

Large Spill

Handling and Storage

Precautions

Exposure Controls/Personal Protection

Engineering Controls

Personal Protection

Personal Protection in Case of a Large Spill

Physical and Chemical Properties

Stability and Reactivity Data

Special Remarks on Reactivity

Toxicological Information

Chronic Effects on Humans

Special Remarks on Chronic Effects on Humans

Special Remarks on other Toxic Effects on Humans

Ecological Information

Products of Biodegradation

Disposal Considerations

Waste Disposal

Transport Information

Other Regulatory Information

Federal and State Regulations

Other Regulations

Other Classifications

DSCL (EEC)

HMIS (U.S.A.)

National Fire Protection Association (U.S.A.)

Protective Equipment

Other Information

SAFETY DATA SHEET

GHS product identifier Other means of

Identification

Supplier's details

Product use : Synthetic/Analytical chemistry

24-hour telephone

Hazards identification

Hazard statements : Flammable gas

Hazard pictograms

Precautionary statements

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations

Hazards not otherwise

Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting

Other means of identification

Substance/mixture

CAS number/other identifiers

Occupational exposure limits, if available, are listed in Section 8

First aid measures

Eye contact

Skin contactInhalation

Description of necessary first aid measures

If it is suspected that fumes are still present, the rescuer should wear a suitable mask, or if it is suspected that fumes are still present, the rescuer should wear a suitable mask or self-contained breathing apparatus.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed

Specific treatments : No specific treatment

Most important symptoms/effects, acute and delayed

Inhalation : Harmful if inhaled

Skin contact : Causes severe burns

Over-exposure signs/symptoms

Skin contact Ingestion

Eye contact : Adverse symptoms may include the following:, pain, watering, rednessPotential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessaryFrostbite: Try to warm up the frozen tissues and seek medical attention

Fire-fighting measures

Hazardous thermal decomposition products

Special protective

Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing

Special protective actions for fire-fighters

Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any

Precautions for safe handling

ACGIH TLV (United States, 3/2017)

OSHA PEL 1989 (United States, 3/1989)

NIOSH REL (United States, 10/2016)

OSHA PEL (United States, 6/2016)

Exposure controls/personal protection

Eye/face protection

Environmental exposure

Appropriate engineering controls

Control parameters

Individual protection measuresOccupational exposure limits

Skin protection

Respiratory protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a

Physical and chemical properties

Physical state

Melting point

Relative density Solubility

Odor pH

Color

Auto-ignition temperatureFlash point

651°C (1203.8°F)Not available

Odor threshold

Partition coefficient: n- octanol/water

Boiling point : -33°C (-27.4°F)

Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: oxidizing materials

Lower and upper explosive (flammable) limits

Heat of combustion : -18589392 J/kgAerosol product

Solubility in water : 540 g/l

Flow time (ISO 2431) : Not available

Vapor pressure

Stability and reactivity

Chemical stability

Possibility of hazardous

Reactivity : No specific test data related to reactivity available for this product or its ingredients

Hazardous decomposition

Incompatible materials

Toxicological information

Acute toxicity

Carcinogenicity Not available

Mutagenicity Not available

Teratogenicity Not available

Reproductive toxicity Not available

Irritation/Corrosion Not available

Sensitization Not available

Information on the likely routes of exposure

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Eye contact : Adverse symptoms may include the following:, pain, watering, rednessSpecific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)Not available

Aspiration hazard Not available

Information on toxicological effects

Potential acute health effects

Developmental effects : No known significant effects or critical hazards

Fertility effects : No known significant effects or critical hazards

Ingestion : Adverse symptoms may include the following:, stomach pains

Potential chronic health effects

Other information : IDLH : 300 ppm

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity Not available

Acute toxicity estimatesPotential immediate

Short term exposure

Potential delayed effects : Not available

Potential immediate

Long term exposure

Ecological information

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards

Toxicity

Persistence and degradability

Soil/water partition

Mobility in soilNot available

Disposal considerations

Disposal of this product, solutions and any by-products must at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste should not be disposed of untreated into the sewer unless in full compliance with the requirements of all authorities having jurisdiction.

Disposal methods

Transport information

AMMONIA, ANHYDROUS

Limited quantity Yes

Special provisions 13,T50

UN number UN proper

Transport hazard class(es)

Packing group

Additional informationEnvironmental

TDG UN1005

OR ANHYDROUS AMMONIA

Explosive Limit and Limited Quantity Index 0 ERAP Index 3000

Passenger Carrying Ship Index Forbidden

Passenger Carrying Road or Rail Index ForbiddenMexico

UN1005 AMMONIA,

DOT Classification

TDG Classification

Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only

Special precautions for user

Transport in bulk according to Annex II of MARPOL and

Special provisions

IMDG IATA

Regulatory information

  • S. Federal regulations

Clean Water Act (CWA) 311: ammonia

Clean Air Act (CAA) 112 regulated toxic substances: ammonia

Massachusetts

SARA 313

Pollutants (HAPs)

Clean Air Act Section 602 Class I Substances

Substances

Precursor Chemicals) : Not listed DEA List II Chemicals

Essential Chemicals)

State regulations

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

SARA 302/304

Composition/information on ingredients

SARA 302 TPQ SARA 304 RQ

SARA 311/312

Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance

New York : This material is listed

New Jersey : This material is listed

Pennsylvania : This material is listed

International regulations

Chemical Weapon Convention List Schedules I, II & III Chemicals

Stockholm Convention on Persistent Organic Pollutants Not listed

Rotterdam Convention on Prior Informed Consent (PIC) Not listed

UNECE Aarhus Protocol on POPs and Heavy Metals Not listed

Inventory list

Australia : This material is listed or exempted

Canada : This material is listed or exempted

China : This material is listed or exempted

Europe : This material is listed or exempted

Japan : Japan inventory (ENCS): This material is listed or exempted

Japan inventory (ISHL): This material is listed or exempted

Republic of Korea : This material is listed or exempted

Malaysia : This material is listed or exempted

New Zealand : This material is listed or exempted

Philippines : This material is listed or exempted

Taiwan : This material is listed or exempted

Turkey : This material is listed or exempted

United States : This material is listed or exempted

Other information

Hazardous Material Information System (U.S.A.) 3

National Fire Protection Association (U.S.A.)Health

The customer is responsible for determining the PPE code for this material. For more information on HMIS®

Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual

1/10/2019History

Date of printing Date of issue/Date of

Version

Notice to reader

Date of previous issue

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor

Special

Instability/ReactivityFlammability

Procedure used to derive the classification

Sodium Sulfite, Anhydrous

  • GHS Label elements, including precautionary statements GHS US labeling
  • Mixtures Not applicable
  • Most important symptoms and effects (acute and delayed) Potential Adverse human health effects and
  • Immediate medical attention and special treatment, if necessary Obtain medical assistance
  • Specific hazards arising from the chemical
  • Other information
  • Possibility of hazardous reactions Contact with acids liberates toxic gas
  • Incompatible materials Strong acids. Strong oxidizers
  • Hazardous decomposition products Sodium oxide. Sulfur compounds
  • Persistence and degradability Sodium Sulfite, Anhydrous (7757-83-7)
  • Bioaccumulative potential Sodium Sulfite, Anhydrous (7757-83-7)

Protection during firefighting: Do not enter the fire area without appropriate protective equipment, including respiratory protection. Health Hazard - Serious eye damage or eye irritation All ingredients in this product are listed or exempted from the United States Environmental Protection Agency's Toxic Substances Control (TSCA) inventory. NFPA Fire Hazard : 0 - Materials that will not burn under typical fire conditions, including essentially noncombustible materials such as concrete, stone, and sand.

NFPA Reactivity : 1 - Materials that are normally stable by themselves but may become unstable at elevated temperatures and pressures. Physical: 1 Slight hazard - Materials that are normally stable but may become unstable (self-reactive) at high temperatures and pressures.

Ethyl Alcohol, 95% v/v

  • Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only
  • Details of the supplier of the safety data sheet Val Tech Diagnostics, A Division of LabChem Inc
  • Hazards identification 2.1. Classification of the substance or mixture
    • Label elements GHS-US labeling
    • Unknown acute toxicity (GHS US) No data available
  • First aid measures 4.1. Description of first aid measures
  • Firefighting measures 5.1. Extinguishing media
    • Advice for firefighters
    • Personal precautions, protective equipment and emergency procedures
    • Environmental precautions Prevent spreading in sewers
    • Exposure controls
    • Chemical stability Hygroscopic
    • Possibility of hazardous reactions Not established
    • Incompatible materials Strong acids. Strong bases
    • Hazardous decomposition products
    • Persistence and degradability Ethyl Alcohol, 95% v/v
    • Bioaccumulative potential Ethyl Alcohol, 95% v/v
    • Mobility in soil Ethyl Alcohol, 95% v/v
    • Other adverse effects
  • Disposal considerations 13.1. Waste treatment methods
  • Transport information In accordance with DOT
    • US State regulations Ethyl Alcohol, 95% v/v()

Different types of hazardous waste should not be mixed together if this could pose a risk of contamination or create problems for further waste management. TP28 - A portable tank with a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Class D Division 2 Subdivision A - Highly toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU Regulations.

Sulfuric Acid, ACS

  • GHS Label elements, including precautionary statements GHS-US labelling
  • Most important symptoms and effects (acute and delayed)
  • Chemical stability Unstable on exposure to moisture
  • Possibility of hazardous reactions
  • Conditions to avoid Incompatible materials. Moisture
  • Incompatible materials
  • Hazardous decomposition products Sulfur compounds
  • Persistence and degradability Sulfuric Acid, ACS (7664-93-9)
  • Bioaccumulative potential Sulfuric Acid, ACS (7664-93-9)

Other hazards that do not result in classification Other hazards that do not contribute to the Other hazards that do not contribute to the. Additional information Strong inorganic acid mists containing sulfuric acid are carcinogenic to humans National Toxicology Program (NTP) Status 2 - Known carcinogens to humans. Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008.

B84 - Packagings must be protected with non-metallic liners that are impervious to the cargo or have a suitable corrosion allowance for sulfuric acid or used sulfuric acid in concentration up to 65.25 percent. DOT Vessel Storage Other : 14 - For metal drums, storage permitted below deck on cargo ships Other information : No additional information available. California Proposition 65 - This product contains no substances known to the State of California to cause cancer, developmental and/or reproductive harm.

Phenolphthalein, ACS

  • Chemical stability Unstable on exposure to light
  • Incompatible materials Strong oxidizers. Strong bases
  • Hazardous decomposition products Carbon dioxide. Carbon monoxide
  • Persistence and degradability Phenolphthalein, ACS (77-09-8)
  • Bioaccumulative potential Phenolphthalein, ACS (77-09-8)
  • Mobility in soil Phenolphthalein, ACS (77-09-8)
  • International regulations

Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified Skin corrosion/irritation : Not classified Serious eye damage/eye irritation : Not classified Respiratory or skin sensitization : Not classified. Ecology - air : Not on the list of substances that can contribute to the greenhouse effect (IPCC).

PENGARUH KADAR KATALIS TERHADAP PEMBUATAN RESIN UREA FORMALDEHID SKALA LABORATORIUM

Abstrak

  • Pendahuluan
  • Tinjauan Pustaka
    • Jenis-jenis Polimer
  • Polimer alam, yaitu polimer yang tersedia di alam. Contohnya karet
  • Polimer sintetik, yaitu polimer buatan hasil sintetis industri atau pabrikan
    • Berdasarkan jenis monomernya 1. Homopolimer, yaitu polimer yang
  • Kopolimer, yaitu polimer yang terbentuk dari beberapa jenis
    • Berdasarkan bentuk susunan rantainya
  • Polimer rantai lurus yaitu polimer yang tersusun dengan unit yang
  • Polimer rantai bercabang yaitu polimer yang terbentuk jika beberapa
  • Polimer berikatan silang yaitu polimer yang terbentuk karena
    • Berdasarkan sifat terhadap panas
  • Polimer termoplas, atau termoplastis yaitu polimer yang melunak jika
  • Polimer termoset, atau termosetting yaitu polimer yang tidak melunak
    • Pengertian Polimerisasi
  • Polimer adisi yaitu polimer yang terbentuk melalui reaksi adisi dari
  • Polimerisasi kondensasi yaitu polimer yang terbentuk karena monomer-
    • Urea Formaldehid
  • Metode Percobaan 3.1 Diagram Alir
    • Alat dan bahan
    • Prosedur percobaan
  • Menambahkan 25 ml sodium sulfat kedalam erlenmeyer. Mereaksikan larutan dengan
    • Hasil dan Pembahasan
    • Daftar Pustaka

Kopolimer yaitu polimer yang terbentuk dari beberapa jenis, terbentuk dari beberapa jenis monomer yang berbeda. Polimer rantai bercabang adalah polimer yang terbentuk ketika banyak polimer terbentuk ketika beberapa rantai berulang membentuk cabang pada rantai utama. Polimer ikatan silang adalah polimer yang dibentuk oleh polimer yang dibentuk oleh beberapa rantai polimer yang bersaing.

Polimer adisi adalah polimer yang dibentuk oleh reaksi adisi monomer yang berbeda. Polimerisasi kondensasi merupakan polimer yang terbentuk karena monomer terbentuk karena monomer tersebut berikatan dengan melepaskan molekul kecil. Pada penelitian ini bahan yang digunakan dalam pembuatan resin urea-formaldehida adalah formalin dan natrium.

Hal ini terjadi karena semakin lama waktu pengadukan, semakin banyak formaldehida yang akan bereaksi dengan urea dan membentuk urea-formaldehida.

Gambar 2 Reaksi Metilolasoi
Gambar 2 Reaksi Metilolasoi

UNILA

Mei 2016 Online 1 Juni 2016

ABSTRAK: Penelitian ini dilakukan untuk mempelajari pengaruh rasio molar formaldehida/urea (F/U) dan jenis katalis terhadap produksi resin urea-formaldehida. ABSTRAK: Penelitian ini dilakukan untuk mengetahui perbandingan molar formaldehida/urea (F/U) dan katalis terhadap pembentukan resin urea-formaldehida. Resin urea formaldehida adalah bahan universal yang banyak digunakan dalam bidang teknik seperti industri pelapisan dan untuk meningkatkan sifat kerapuhan dan ketahanan air.

Resin Urea-formaldehida (UF) merupakan resin pengikat utama untuk interior panel komposit kayu, seperti; papan serat kepadatan sedang dan kayu lapis kayu keras. Hasil reaksi antara urea dan formaldehida mempunyai sifat tahan terhadap asam, basa, tidak dapat larut dan tidak dapat meleleh yang merupakan bagian dari golongan termoset. Polimer termoset dihasilkan dengan menggabungkan komponen-komponen yang saling menguatkan sehingga menjadi suatu polimer dengan a Tingkat ikatan silang yang sangat tinggi dihasilkan. Resin urea-formaldehida biasanya menghasilkan produk yang lebih unggul dibandingkan plastik, tetapi hanya dapat digunakan pada interior non-struktural.

Produksi urea formaldehida dalam kondisi basa terdiri dari reaksi substitusi di mana formaldehida bereaksi dengan urea membentuk urea metilol dengan derajat metilol yang bervariasi (derajat substitusi dengan gugus metilol).

22 sepertiga dari nilai yang ditemukan dalam karya de Jongdan

Metode Percobaan

  • Pembuatan Resin Urea-Formaldehid
  • Analisa Formaldehid Bebas
  • Analisa Viskositas
  • Analisa Densitas

Hasil dan Pembahasan

  • Pengaruh Variasi F/U terhadap Densitas

24 Hubungan densitas (kg/m3) terhadap perubahan waktu

  • Pengaruh Variasi F/U terhadap Viskositas
  • Kesimpulan
  • Ucapan Terimakasih
  • Daftar Pustaka

Berdasarkan hasil percobaan dapat disimpulkan bahwa massa jenis resin urea-formaldehida pada F/U 2 dengan katalis NaOH adalah 1370 kg/m3 dan katalis NH4OH adalah 1370 kg/m3, sedangkan viskositas dengan katalis NaOH adalah kg. /m.s, dan katalis NH4OH sebesar 0,00827 kg/m.s. Ivana, G., Olivera N., Milanka D., 2010, Distribusi massa molar resin urea-formaldehida dengan tingkat polimerisasi berbeda dengan spektrometri massa MALDI-TOF. Miljkoviḉ, Jovan., Grmusa, Ivana-Gavrilovic., Momcilovic, Milanka Diporovic., Popovic, Mladan., 2006, Beberapa karakteristik perekat bubuk urea-formaldehida, 223-230.

Osemeahon, S.A., Maitera, O.N., Hotton, A.J., Dimas, BJ., 2013, Effect of starch addition on properties of urea formaldehyde/starch copolymer blends for use as a binder in the coatings industry. Wang, Dang-Liang., Bai, Han-Ying., Yue, Gao., 2013, Gel characteristics of urea-formaldehyde resin under shear flow conditions. Research paper. Summary: The urea-formaldehyde fl!adion is a stepwise reaction, the first step being the formation of methylol from the urea-formaldehyde addition reaction.

Ada beberapa kemungkinan struktur polimer hasil kondensasi urea-formaldehida yang dikemukakan oleh para ahli, salah satunya dikemukakan oleh Hodgkr dan Hovey yang mengusulkan struktur tiga dimensi linier.

Gambar 5. Grafik Penentuan orde (a) katalis NH 4 OH (b) katalis NaOH
Gambar 5. Grafik Penentuan orde (a) katalis NH 4 OH (b) katalis NaOH

Gambar

Gambar 4.2.3 Orde reaksi dari variasi katalis 1%
Gambar 4.2.4  Orde reaksi dari variasi katalis 2%
Gambar 4.2.5  Orde reaksi dari variasi katalis 3%
Gambar 4 Diagram alir analisa formaldehid bebas  Gambar 3 Diagram alir pembuatan urea-formaldehid
+7

Referensi

Dokumen terkait

By modifying equation 6 above, the link between natural resources endowment and manufacturing sector performance can thus be simplified in equation 7 below as follows where =

1 1Kazakh national pedagogical University named after Abai, Almaty, Kazakhstan EDUCATIONAL RESOURCE IN IMPROVING THE QUALITY OF EDUCATION OF COLLEGE STUDENTS – THE USE OF IN